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001-es BibID:BIBFORM079636
Első szerző:Lente Gábor (vegyész)
Cím:Analytical solutions for the rate equations of irreversible two-step consecutive processes with mixed second order later steps / Lente Gábor
Dátum:2017
ISSN:0259-9791
Megjegyzések:A general strategy was developed to solve the ordinary differential equations defined by two-step chemical processes with a mixed second order later process for all possible cases of parameter values (initial concentrations and rate constant values). As the earlier process, first order, second order, mixed second order and zeroth order cases were considered. For the scheme with a mixed second order first step, several different variations were considered. The analytical solutions contain moderately advanced, but still elementary functions such as the error function, the incomplete gamma function, the hypergeometric function or the Legendre functions. When coupling between the two steps or some reversibility is present in the system, no analytical solutions are found.
Tárgyszavak:Természettudományok Kémiai tudományok idegen nyelvű folyóiratközlemény külföldi lapban
Mixed second order kinetics
Rate equation
Reaction kinetics
Mathematical modelling
Intermediate
Biphasic process
Megjelenés:Journal Of Mathematical Chemistry. - 55 : 3 (2017), p. 832-848. -
Pályázati támogatás:GINOP-2.3.2-15-2016-00008
GINOP
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