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001-es BibID:	BIBFORM104060
035-os BibID:	(cikkazonosító)5352 (WOS)000594885900001 (Scopus)85096407892
Első szerző:	Udvardy Antal (vegyész)
Cím:	Mechanochemical P-derivatization of 1,3,5-Triaza-7-Phosphaadamantane (PTA) and Silver-Based Coordination Polymers Obtained from the Resulting Phosphabetaines / Antal Udvardy, Csenge Tamara Szolnoki, Réka Gombos, Gábor Papp, Éva Kováts, Ferenc Joó, Ágnes Kathó
Dátum:	2020
ISSN:	1420-3049
Megjegyzések:	We have described earlier that in aqueous solutions, the reaction of 1,3,5-triaza-7-phosphaadamantane (PTA) with maleic acid yielded a phosphonium-alkanoate zwitterion. The same reaction with 2-methylmaleic acid (citraconic acid) proceeded much slower. It is reported here, that in the case of glutaconic and itaconic acids (constitutional isomers of citraconic acid), formation of the corresponding phosphabetaines requires significantly shorter reaction times. The new phosphabetaines were isolated and characterized by elemental analysis, multinuclear NMR spectroscopy and ESI-MS spectrometry. Furthermore, their molecular structures in the solid state were determined by single crystal X-ray diffraction (SC-XRD). Synthesis of the phosphabetaines from PTA and unsaturated dicarboxylic acids was also carried out mechanochemically with the use of a planetary ball mill, and the characteristics of the syntheses in solvent and under solvent-free conditions were compared. In aqueous solutions, the reaction of the new phosphabetaines with Ag(CF3SO3) yielded Ag(I)-based coordination polymers. According to the SC-XRD results, in these polymers the Ag(I)-ion coordinates to the N and O donor atoms of the ligands; however, Ag(I)-Ag(I) interactions were also identified. The Ag(I)-based coordination polymer (CP1.2) formed with the glutaconyl derivative of PTA (1) showed considerable antimicrobial activity against both Gram-negative and Gram-positive bacteria and yeast strains.
Tárgyszavak:	Természettudományok Kémiai tudományok idegen nyelvű folyóiratközlemény külföldi lapban folyóiratcikk antimicrobial activity ball mill coordination polymer mechanochemistry phosphonium salt silver
Megjelenés:	Molecules. - 25 : 22 (2020), p. 1-18. -
További szerzők:	Szolnoki Csenge Tamara (1992-) (Okleveles vegyész) Borsi-Gombos Réka (1985-) (okleveles biomérnök) Papp Gábor (1976-) (vegyész, kémikus) Kováts Éva (1977-) (vegyész) Joó Ferenc (1949-) (vegyész) Kathó Ágnes (1954-) (vegyész, kémikus)
Pályázati támogatás:	GINOP-2.3.2-15-2016-00008 GINOP GINOP-2.3.3-15-2016-00004 GINOP ED_18-1-2019-002 Egyéb NKFIH-FK-128333 Egyéb
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