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001-es BibID:BIBFORM120195
035-os BibID:(cikkazonosító)023501 (Scopus)85190143595 (WoS)001198354900001
Első szerző:Fábri Csaba
Cím:Classical and quantum light-inducednon-adiabaticity in molecular systems / Csaba Fábri, András Csehi, Gábor J. Halász, Lorenz S. Cederbaum, Ágnes Vibók
Dátum:2024
ISSN:2639-0213
Megjegyzések:The exchange of energy between electronic and nuclear motion is the origin of non-adiabaticity and plays an important role in many molecular phenomena and processes. Conical intersections (CIs) of different electronic potential energy surfaces lead to the most singular non-adiabaticity and have been intensely investigated. The coupling of light and matter induces conical intersections, which are termed light-induced conical intersections (LICIs). There are two kinds of LICIs, those induced by classical (laser) light and those by quantum light like that provided by a cavity. The present work reviews the subject of LICIs, discussing the achievements made so far. Particular attention is paid to comparing classical and quantum LICIs, their similarities and differences and their relationship to naturally occurring CIs. In contrast to natural CIs, the properties of which are dictated by nature, the properties of their light-induced counterparts are controllable by choosing the frequency and intensity (or coupling to the cavity) of the external light source. This opens the door to inducing and manipulating various kinds of non-adiabatic effects. Several examples of diatomic and polyatomic molecules are presented covering both dynamics and spectroscopy. The computational methods employed are discussed as well. To our opinion, the young field of LICIs and their impact shows much future potential.
Tárgyszavak:Természettudományok Fizikai tudományok idegen nyelvű folyóiratközlemény külföldi lapban
folyóiratcikk
Cavity-induces
non-adiabatic
phenonema
Megjelenés:AVS Quantum Science. - 6 : 2 (2024), p. 1-19. -
További szerzők:Csehi András (1986-) (fizikus) Halász Gábor J. (1961-) (fizikus) Cederbaum, Lorenz S. Vibók Ágnes (1962-) (fizikus)
Pályázati támogatás:K128396
OTKA
K146096
OTKA
Deutsche Forschungsgemeinschaft(DFG)Grant No. CE 10/56-1
Egyéb
BO/00474/22/11
Egyéb
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